Product ID:AQUEOUS AMINE SOLUTION
MSDS Date:03/28/1990
FSC:6850
NIIN:00N017171
MSDS Number: BLCCQ

CALGON CORPORATION

PITTSBURGH, PA 15230-1346
US

Emergency Phone: 412-777-8000

Info Phone: 412-777-8000

Preparer: P J MALONEY

Cage: EO504

CALGON CORPORATION

1346 PITTSBURG, PA 15230-1346 US

Telephone: 412-494-8000

Cage: EO504

OVEREXP TO MIST/VAP MAY

RTECS: 9999999ZZ

LIGHTHEADEDNESS, DROWS & ANXIETY. RPTD INHAL MAY

RTECS: 9999999ZZ

RATS SHOWED PULM EDEMA/LIVER NECROSIS/RENAL TUBULAR

RTECS: 9999999ZZ

CYCLOHEXYLAMINE HAS CAUSED EMBROYTOX & REPRO

RTECS: 9999999ZZ

BEEN SEEN AT INDUSTRIALLY RELEVANT LEVELS IN HUMANS.

RTECS: 9999999ZZ

EXPOS TO CYCLOHEXYLAMINE. IN SUBACUTE FEEDING

RTECS: 9999999ZZ

OF INTENSE IRRITATION OF INTESTINAL TRACT AND

RTECS: 9999999ZZ

INJURY W/INCR DOSES. SKIN, LIVER/KIDNEY INJURY WAS

RTECS: 9999999ZZ

TO RABBITS. RPPTD EXPOS OF RATS/GPGS TO MORPHOLINE

RTECS: 9999999ZZ

BRONCHI & BRONCHIOLES, & KIDNEY & LIVER SECTIONS

RTECS: 9999999ZZ

ONCOGENIC STUDY W/MORPHOLINE WAS NEGATIVE IN RATS.

RTECS: 9999999ZZ

FULL LENGTH FACESHIELD TO GOGGLES .

RTECS: 9999999ZZ

MORPHOLINE

CAS: 110-91-8

RTECS: QD6475000

Fraction By Weight: 33%

OSHA PEL S,20 PPM/30 STEL

ACGIH TLV: S, 20 PPM; 9192

CYCLOHEXYLAMINE (SARA III)

CAS: 108-91-8

RTECS: GX0700000

Fraction By Weight: 11%

OSHA PEL 10 PPM

ACGIH TLV: 10 PPM; 9192

PRESENT. BASED ON LOW RABBIT SKIN PENETRATION

RTECS: 9999999ZZ

POTENTIALLY TOXIC BY SKIN ABSORPTION. THEREFORE,

RTECS: 9999999ZZ

HARMFUL AMOUNTS OF THIS MATL. SYMPS OF OVEREXP WOULD

RTECS: 9999999ZZ

HARMFUL IF SWALLOWED. HIGH PH WOULD INDICATE THAT

RTECS: 9999999ZZ

ESOPHAGUS, & STOMACH. ONE SOURCE SAYS THAT ACUTE ORAL

RTECS: 9999999ZZ

CYCLOHEXYLAMINE. THEREFORE, PROD WOULD BE CONSIDERED

RTECS: 9999999ZZ

COULD INCLUDE NAUSEA, VOMIT, ANXIETY, RESTLESSNESS,

RTECS: 9999999ZZ

CYCLOHEXYLAMINE IS WEAK METHEMOGLOBIN-FORMING

RTECS: 9999999ZZ

LD50 LC50 Mixture:SEE INGREDIENTS.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS:EYE, SKIN, LUNGS, LIVER,
KIDNEYS, BLOOD. DANGER! MAY CAUSE SEVERE EYE/SKIN DAMAGE. MAY BE
HARMFUL IF ABSORBED THROUGH SKIN OR IF SWALLOWED. MAY CAUSE AN
ALLERGIC SKIN REACTION. MAY CAUSE RESP TRACT IRRIT. MAY FORM
SUSPECTED CANCER-CAUSING NITROSAMINES IF MIXED W/NITRITES.
ACUTE:EYE:PROD (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:WOULD BE EXPECTED TO CAUSE SEVERE EYE
IRRIT ON CONTACT & POSS PERM INJURY. EXPOS TO VAPS MAY CAUSE
DEVELOPMENT OF CORNEAL OPACITIES. AT LOW CONC IN AIR, MORPHOLINE
HAS CAUSED TRANSIENT CORNEA L EDEMA & TEMPORARY FOGGY VISION
W/HALOS AROUND LIGHTS IN WORKERS EXPOSED FOR MANY HOURS. THESE
SYMPS APPEAR(SUPP DATA)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYE:IMMED FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MIN.GET MD
IMMED. SKIN:IMMED FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINS
WHILE REMOVING CONTAM CLTHG/SHOES. GET MD IMMED. WASH CLTHG BEFORE
REUSE. IN GEST:DO NOT INDUCE VOMIT. GIVE LGE QTYSOF WATER. GET MD
IMMED. NEVER GIVE ANYTHING BY MOUTH TO UCNON PERSON. INHAL:IF
IRRRIT OR DFCLTY BRTHG, REMOVE TO FRESH AIR.GET MD IF
IRRIT/DISCOMFORT PERSISTS.

Flash Point Method:TCC
Flash Point:125F,52C
Extinguishing Media:DRY CHEMICAL, "ALCOHOL" FOAM, CO*2, OR WATER SPRAY.
Fire Fighting Procedures:EXCERCISE CAUTION WHEN FIGHTING FIRE. WEAR
NIOSH/MSHA APPRVD SCBA AND FULL PROTECTIVE EQUIPMENT . USE WATER TO
KEEP FIRE EXPOSED CONTAINERS COOL.
Unusual Fire/Explosion Hazard:EMITS TOXIC GASES UNDER FIRE CNDTNS.
MORPHOLINE VAP & CYCLOHEXYLAMINE VAP ARE HEAVIER THAN AIR & MAY
TRAVEL A CONDISERABLE DISTANCE TO A SOURCE OF (SUPP DATA)

Spill Release Procedures:VENT AREA OF SPILL & REMOVE ALL SOURCES OF
IGNITION. WEARING APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT,
CONTAIN SPILL, COLLECT ONTO INERT ABSORBENT AND PLACE INTO SUITABLE
CONTAINER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP AWAY FROM HEAT AND FLAME. USE
WITH ADEQUATE VENTILATION. KEEP CONTAINER CLOSED WHEN NOT IN USE.
WASH THOROUGHLY AFTER HANDLING.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.

Respiratory Protection:IF AIRBORNE CONC EXCEED PUBLISHED EXPOSURE
LIMITS, USE AN NIOSH/MSHA APPROVED RESPIRATOR IN ACCORDANCE WITH
OSHA RESPIRATORY PROTECTION REQUIREMENTS (29 CFR 1910.134).
Ventilation:LOCAL EXHAUST VENTILATION MAY BE REQUIRED IN ADDITION TO
GENERAL ROOM VENT TO MAINTAIN AIRBORNE CONC BELOW EXPOS LIMITS.
Protective Gloves:CHEMICAL RESISTANT GLOVES.
Eye Protection:CHEM WORKERS GOG, MAY ADD (SEE ING 22).
Other Protective Equipment:PROTECTIVE CLOTHING. EYE WASH STATION AND
SAFETY SHOWER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXPLO HAZ:IGNIT & FLASH BACK. CLSD CNTNRS MAY RUPTURE DUE TO PRESS
BUILDUP WHEN EXPOSED TO EXTREME HEAT. EFTS OF OVEREXP:AFTER WORK &
MAY DISAPPEAR BY NEXT DAY. SKIN:PROD WOULD BE EXPECTED TO CAUSE SE
VERE IRRIT ON CNTCT & POSS SKIN BURNS. VAPS MAY ALSO BE IRRIT. PROD
MAY BE SKIN SENSIT DUE TO CYCLOHEXYLAMINE(SEE ING 3)

Spec Gravity:1-1.02
pH:12.3
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR, PALE YELLOW LIQUID WITH AMINE ODOR.
Percent Volatiles by Volume:98

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS AND STRONG ACIDS.
Stability Condition to Avoid:KEEP AWAY FROM HEAT AND FLAME.
Hazardous Decomposition Products:CO, CO*2, AMMONIA, DISODIUM OXIDE, AND
OXIDES OF NITROGEN.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.